Hydrogen storage in Ca-amidoborane

Molecular model systems for the Ca-catalyzed dehydrogenation of ammonia-borane aid in understanding the intricate details of the mechanisms.

J. Am. Chem. Soc. 2009, 131, 5064
Hydrogen Elimination in Bulky Calcium Amidoborane Complexes: Isolation of a Calcium Borylamide Complex

Angew. Chem., Int. Ed. 2008, 47, 6290-6295
Calcium Amidoborane Hydrogen Storage Materials: Crystal Structures of Decomposition Products
DOI: Angew. Chem. Int. Ed.10.1002/anie.200802037

Chem. Soc. Rev. 2016, 45, 1112
s-Block amidoboranes: syntheses, structures, reactivity and applications
DOI:10.1039/C5CS00544B